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 Organization

NO 71
Acronym UBAG
Name German Environment Agency
Address 1 Umweltbundesamt, Wörlitzer Platz 1, 06844 Dessau-Roßlau
Address 2 Umweltbundesamt (Federal Environment Agency) FG II4.5, Air Monitoring Network, Paul-Ehrlich-Str. 29, 63225 Langen
Address 3
Country/Territory Germany
Website https://www.umweltbundesamt.de/gaw

 Contact(s)

Name Cedric Couret
Prefix Ing.
Email cedric.couret@uba.de
Organization No 71
Organization acronym UBAG
Organization name German Environment Agency
Organization country/territory Germany
Address 1 Umweltbundesamt, Umweltforschungsstation Schneefernerhaus, Zugspitze 5, 82475 Zugspitze
Address 2
Address 3
Country/territory Germany
Tel +498821924110
Fax
Last updated date 2023-07-12


 Background observation
 UTC
 ppb
 2002-01-01 00:00:00 - 9999-12-31 23:59:59: WMO CH4 X2004A
 2001-01-01 00:00:00 - 2011-12-31 22:59:59: Hewlett Packard Modified HP 6890 Chem. station, # US00030144(Gas chromatography (FID))
 2011-12-31 23:00:00 - 2014-12-31 22:59:59: Picarro Envirosense 3000i(CRDS)
 2014-12-31 23:00:00 - 2015-12-31 22:59:59: Hewlett Packard Modified HP 6890 Chem. station, # US00030144(Gas chromatography (FID))
 2015-12-31 23:00:00 - 2023-03-31 23:59:59: Picarro G2301, ICOS #880(CRDS)
 2022-01-01 00:00:00 - 9999-12-31 23:59:59: Picarro G2401, ICOS #1167(CRDS)
 2001-01-01 00:00:00 - 9999-12-31 23:59:59: 3.00 (m)
 1 minute
 All data are based on WMO mole fraction scale. (NOAA/CMDL)
Calibration of the GC Data CO2 and CH4:
Calibration gas: CO2 in natural air. Calibrations are carried out every 15 minutes using working standard tanks, which have been calibrated by the use of a group of 6 NOAA station standards from the NOAA/CMDL Carbon Group for CO2 and CH4. The NOAA station standards envelope the actual atmospheric concentrations of CO2 and CH4
Current Scale: WMO mole fraction scale
The usual sequence is sample,sample,standard. Each chromatogram takes 5 minutes
GC Measurement data evaluation via Chemstation software.

Calibration of the Picarro 2301 Data CO2 and CH4 until the 12th of January 2021:
Calibration gas: CO2 and CH4 in natural air. The correction of the data is carried out every 8 hours using a short term standard tank. The short term tank is calibrated every 3 days by the use of 2 Standard tanks: 1 High and 1 low.
The high and low standards are calibrated every 2 months by the use of a group of 4-6 NOAA station standards from the NOAA/CMDL Carbon Group.
A target tank is measured every 3 days to detect any drift/issue.
The NOAA station standards envelope the actual atmospheric concentrations of CO2 and CH4.
Current Scale: WMO mole fraction scale

From the 13th of January 2021, ICOS standard are used to calibrate the instruments.
 All values are quality controlled.

Processing of GC Data
With a software, called GC-Organizer, written by the team of I.Levin at University of Heidelberg the measured 5 min raw data are visually controlled in respect to outliers and the standard deviation during measurement of the standards. Outliers are removed with this graphical tool. After this pre-check 30 min atmospheric concentrations and standard deviation of CO2, CH4, SF6 and N2O are calculated with the same software program.
Afterwards these 30 min data are imported with a self written software program, called Dafit (Description see: www.gawstat.de).
The 30 min data are screened graphically. For a second validation, episodes of local pollution, also power failures, Instrument repairs etc. can be flagged. The digital log-book and if required, trajectories and co correlation with simultaneously measured data are used in to verify the CO2, CH4, N2O and SF6 data.
Then from the flagged data for scientific purpose and export aggregation to 60min, 1day and 1month data is calculated in a standardized way for each, simultaneously also files with the WDCGG export format are produced in a standardized way to automate the workflow.

Processing of Data from CRDS (Picarro, CO2, CH4 ) and QCL (Los Gatos, N2O, CO)
The data acquisition system provides 1-minute averages of the raw data.
1 min data of sample and measurement of calibration gases are automatically retrieved and the data are automatically corrected. Calibration factors are used to convert 1-minute averages into calibrated 1-minute averages.
With a self written software program, called Dafit (description see: www.gawstat.de) the data are imported.
The data are visualized and artefacts, like spikes, room air, instrument repair, calibrations or mixed air data are flagged.
After this step, hourly, daily and monthly means are calculated.

Processing from 13.01.2021: Data processing at ICOS ATC is described in [Hazan et al., 2016], doi:10.5194/amt-9-4719-2016
 [Hourly] Mean Processing for the GC-data CO2, CH4, N2O and SF6
The data acquisition system provides one value every five minutes raw data. Zero/calibration factors and data protocols are used to convert raw data into calibrated data. Invalid data caused by local impact, malfunction or other effects are detected by comparison/ correlation with other trace substances and meteorological data and with information from the station logbook and then are rejected. 30 min mean values are generated by calculating the arithmetic mean of the remaining data.
For reporting to WDCGG hourly mean values are calculated from these half hourly data.

Mean Processing for the Picarro 2301 data CO2 and CH4
Hourly mean values are generated by calculating the arithmetic mean of the available data within the respective hour.
nvalue refers to the number of available 1-minute averages within the respective hour.

Mean Processing from 13.01.2021:
Data processing at ICOS ATC is described in [Hazan et al., 2016], doi:10.5194/amt-9-4719-2016
 [Daily] Mean Processing for the GC-data CO2, CH4, N2O and SF6
Daily mean values are generated by calculating the arithmetic mean of the available hourly data within the respective day.
nvalue refers to the number of available hourly averages within the respective day.

Mean Processing for the Picarro 2301 data CO2 and CH4
Daily mean values are generated by calculating the arithmetic mean of the available hourly data within the respective day.
nvalue refers to the number of available hourly averages within the respective day.

Mean Processing from 13.01.2021:
Data processing at ICOS ATC is described in [Hazan et al., 2016], doi:10.5194/amt-9-4719-2016
 [Monthly] Mean Processing for the GC-data CO2, CH4, N2O and SF6
Monthly mean values are generated by calculating the arithmetic mean of the available daily data within the respective month.
nvalue refers to the number of available daily averages within the respective month.

Mean Processing for the Picarro 2301 data CO2 and CH4
Monthly mean values are generated by calculating the arithmetic mean of the available daily data within the respective month.
nvalue refers to the number of available daily averages within the respective month.

Mean Processing from 13.01.2021
Data processing at ICOS ATC is described in [Hazan et al., 2016], doi:10.5194/amt-9-4719-2016
 Until 12.01.2021,
1: Valid
3: Not Valid

From 13.01.2021
Flag 'U' = data correct before manual quality control
Flag 'N' = data incorrect before manual quality control
Flag 'O' = data correct after manual quality control
Flag 'K' = data incorrect after manual quality control
Flag 'R' = data correct after manual quality control and backwards propagation
Flag 'H' = data incorrect after manual quality control and backwards propagation
 Valid (background): 1
 Invalid: 3
 Valid (background): U
 Invalid: N
 Valid (background): O
 Invalid: K
 Valid (background): R
 Invalid: H
 Operational/Reporting
 Gas chromatography followed by flame ionisation detection (FID)
especially designed GC unit, project of university Heidelberg for Umweltbundesamt
 Wind direction: 1
 Wind speed: 1
 Relative humidity: 1
 Precipitation amount: 0
 Air pressure: 1
 Air temperature: 1
 Dew point temperature: 1
 Sea water temperature: 0
 Sea surface water temperature: 0
 Sea water salinity: 0
 Sea surface water salinity: 0
Meteorological data may remain as first provided, even when greenhouse gas data are updated.
 
No DOI available

 Related information

Format Text (WDCGG Data Format Table, WDCGG Meteorological Data Format Table), NetCDF
Relation List (Is Part Of) All CH4 data contributed to WDCGG by GAW stations and mobiles by 2023-09-13
All CH4 data contributed to WDCGG by GAW stations and mobiles by 2022-09-07
All CH4 data contributed to WDCGG by GAW stations and mobiles by 2021-08-27
All CH4 data contributed to WDCGG by GAW stations and mobiles by 2020-09-28
All CH4 data contributed to WDCGG by GAW stations and mobiles by 2019-09-19
All CH4 data contributed to WDCGG by GAW stations and mobiles by 2018-10-25
Geolocation Point
Latitude (north: +; south: -) 47.4165
Longitude (east: +; west: -) 10.97964

 GAW Data Policy

"For Scientific purposes, access to these data is unlimited and provided without charge. By their use you accept that an offer of co-authorship will be made through personal contact with the data providers or owners whenever substantial use is made of their data. In all cases, an acknowledgement must be made to the data providers or owners and to the data centre when these data are used within a publication."

 Citation format

This format is an example of the WDCGG standard citation.
Please follow the citation format which the data providers or owners indicate.
Cedric Couret (UBAG), Atmospheric CH4 at Zugspitze-Schneefernerhaus by German Environment Agency , dataset published as CH4_ZSF_ surface-insitu_UBAG_data1 at WDCGG, ver. 2023-07-12-0734 (Reference date*: YYYY/MM/DD)

* As the reference date, please indicate the date you downloaded the files.

 Reference(s)

1  System and Performance Audit of Surface Ozone, Carbon Monoxide, Methane, Carbon Dioxide and Nitrous Oxide at the Global GAW Station Zugspitze-Schneefernerhaus Germany, September 2020

https://library.wmo.int/doc_num.php?explnum_id=10747
2  Data processing at ICOS ATC is described in [Hazan et al., 2016], doi:10.5194/amt-9-4719-2016