In line with the GAW Data Policy, users should contact the contributors of all data of interest and propose co-authorship or acknowledgement.
Organization
| NO | 20 |
|---|---|
| Acronym | ECCC |
| Name | Environment and Climate Change Canada |
| Address 1 | Environment and Climate Change Canada |
| Address 2 | Climate Research Division |
| Address 3 | 4905 Dufferin Street, Toronto, Ontario CANADA M3H 5T4 |
| Country/Territory | Canada |
| Website |
Contact(s)
| Name | Lin Huang |
|---|---|
| Prefix | Dr. |
| lin.huang@canada.ca | |
| Organization No | 20 |
| Organization acronym | ECCC |
| Organization name | Environment and Climate Change Canada |
| Organization country/territory | Canada |
| Address 1 | |
| Address 2 | |
| Address 3 | |
| Country/territory | Canada |
| Tel | (416) 739-5821 |
| Fax | (416) 739-4106 |
| Last updated date | 2021-04-30 |
| Background observation | |
| UTC | |
| permil | |
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9999-12-31 00:00:00 - 9999-12-31 23:59:59: VPDB-CO2 |
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9999-12-31 00:00:00 - 9999-12-31 23:59:59: Thermo Finnigan MAT252(Mass spectrometry) |
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9999-12-31 00:00:00 - 9999-12-31 23:59:59: 60 (m) |
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| weekly | |
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1). Each analysis is carried out by extracting CO2 from a 2L flask sample, followed by a flaming seal in an ampoule and then measured its isotopic composition relative to CO2 gas in a reference bellow by the IRMS(MAT252), at the same time, the primary anchor (see below) is also measured as the sample; 2). Each sample is linked to VPDB-CO2 scale via the primary anchor. The isotope ratios are reported in units of per mil Where: δ13C = [(13C/12Csamp/ (13C/12Cstd/)-1] x 1000 ‰ Measurement precision of IRMS is 0.01 per mil; 3). The overall uncertainty (in terms of accuracy and precision) of individual samples in δ13C is < 0.02 permil. |
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| 17O correction is done using Allison/Craig correction | |
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[Hourly] [Daily] [Monthly] |
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Three-Column quality control flags: a NOAA 3-column quality control flag has been adopted where each column is defined as follows: [column 1] Hard REJECTION flag. *.. The sample doesn't have a pair; +.. high member of the bad pair (pair rejection criteria: 0.05 permil for δ13C and 0.15 permil for δ18O); -.. low member of the bad pair (pair rejection criteria: 0.05 permil for δ13C and 0.15 permil for δ18O); [column 2] SOFT REJECTION flag. A star other than a period (.) in the SECOND column indicates a sample that is likely valid but does not meet selection criteria determined by the goals of a particular investigation (e.g., the sample may not represent the background condition). [column 3] COMMENT flag. An alphanumeric other than a period (.) in the THIRD column provides additional information about the collection or analysis of the sample (e.g., ""..I"" indicates an ICP sample which have been measured by more than one lab). If both the first and second column contain a period (e.g., ""..."" and ""..I""), the sample is RETAINED. |
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Valid (background): ... Valid: *.. Valid: .*. Invalid: +.. Invalid: -.. |
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| Terminated | |
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Other Descriptions for Sampling and Analyses: Environment Canada installed an auto flask sampling at the site in 2007. Each week, a pair of flasks has been sampled by pressurizing air into the 2-litre double-valve flasks. To catch the diurnal change, one flask was sampled in the afternoon and one was sampled in the midnight. These samples are taken at the 40-metre level of a surface tower. The document below should be referred for the details of analysis. (http://www.atmos-meas-tech.net/6/1685/2013/amt-6-1685-2013.html) Scale and Calibration (traceability): 1) The internationally accepted scale for reporting δ13C is VPDB-CO2 (Vienna Pee Dee Bellemnite); 2). The primary anchor to the VPDB-CO2 scale for CO2 isotope measurements is the pure CO2 evolved from a carbonate (i.e., Cal2) reference materials; 3). Annual calibration is conducted via measuring the primary anchor together with the international reference materials NBS19 and NBS18 (linked to VPDB-CO2). The detailed information for calibration and traceability of the measurements can be found in the reference (http://www.atmos-meas-tech.net/6/1685/2013/amt-6-1685-2013.html). 4). The overall uncertainty (in terms of accuracy and precision) of individual reference materials in δ13C is < 0.02 permil. |
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Wind direction: Wind speed: Relative humidity: Precipitation amount: Air pressure: Air temperature: Dew point temperature: Sea water temperature: Sea surface water temperature: Sea water salinity: Sea surface water salinity: |
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Meteorological data may remain as first provided, even when greenhouse gas data are updated. |
DOI Metadata
| DOI |
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||||
|---|---|---|---|---|---|
| Version |
2021-04-30-1104 (Data Version History) * DOIs and file names may have multiple versions. Be sure to check the data version. |
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| Title | Atmospheric 13CO2 at Churchill by Environment and Climate Change Canada, dataset published as 13CO2_CHL_surface-flask_ECCC_data1 at WDCGG | ||||
| Creator |
Environment and Climate Change Canada Lin Huang (ECCC) |
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| Publisher | World Data Centre for Greenhouse Gases | ||||
| Publication Date | 2018-06-08 (Last Updated: 2021-04-30) | ||||
| Format | Text (WDCGG Data Format Table, WDCGG Meteorological Data Format Table), NetCDF | ||||
| Relation List (Is Part Of) |
All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2024-08-13 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2023-07-20 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2022-07-12 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2021-07-20 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2020-09-14 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2019-09-19 All 13CO2 data contributed to WDCGG by GAW stations and mobiles by 2018-10-18 |
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| Geolocation Point |
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GAW Data Policy
"For Scientific purposes, access to these data is unlimited and provided without charge.
By their use you accept that an offer of co-authorship will be made through personal contact with the data providers
or owners whenever substantial use is made of their data.
In all cases, an acknowledgement must be made to the data providers or owners and to the data centre when these data are used within a publication."
Citation format
This format is an example of the WDCGG standard citation.
Please follow the citation format which the data providers or owners indicate.
Please follow the citation format which the data providers or owners indicate.
Lin Huang (ECCC),
Atmospheric 13CO2
at Churchill by Environment and Climate Change Canada
,
dataset published as 13CO2_CHL_
surface-flask_ECCC_data1 at WDCGG,
ver. 2021-04-30-1104, https://doi.org/10.50849/WDCGG_0020-4004-1102-01-02-9999 (Reference date*: YYYY/MM/DD)
* As the reference date, please indicate the date you downloaded the files.
* As the reference date, please indicate the date you downloaded the files.
Reference(s)
| 1 | Huang, L., A. Chivulescu, D. Ernst, W. Zhang, A.-L. Norman, Y.-S. Lee (2013) Maintaining Consistent traceability in High Precision Isotope Measurements in CO2: a way to verify long-term Atmospheric trends of δ13C and δ18O, Atmos. Meas. Tech., 6, 1685-1075, 2013/ www.atmos-meas-tech.net/6/1685/2013/ doi:10.5194/amt-6-1685-2013. |
|---|---|
| 2 | Huang L.,, A. Chivulescu, C. Allison, G. Brailsford, W. A. Brand, M. Wendeberg, A. Bollenbacher, R. Keeling, I. Levin, M. Sabasc6, M. Leuenberger, H. Mukai, T. Nakazawa, S. Aoki, R. Neubert, A. Aerts-Bijma, M. Verkouteren, J. White, B. Vaughn, S. Michel, L. Zhou, L.X. Liu (2011) A Report of δ13C & δ18O Measurements in NBS19 and NBS18 pure CO2: Uncertainty in Traceability of CO2 Isotope Measurements, In the proceeding of Report to the 15thWMO/IAEA CO2 Expert Meeting, Jena, Sept. 2009. WMO Report |
| 3 | Brand, Willi A., L. Huang, H. Mukai, A. Chivulescu, Ju¨rgen M. Richter & Michael Rothe (2009) How well do we know VPDB? Variability of δ13C and δ18O in CO2 generated from NBS19-calcite, Rapid Commun. Mass Spectrom. 2009; 23: 915-926. |
| 4 | Huang, L. and D. Worthy (2005) Flask Sampling Strategy by MSC for Atmospheric Observations of Greenhouse Gases and CO2 Isotopes over Canada: Status & Plan, Report of the 12th WMO/IAEA Meeting of Experts on CO2 Concentration and Related Tracer Measurement Techniques, Toronto, Sept. 2003, GAW publication 161, 94-100., May, 2005. |
